The Influence of Fluoride Anion on the Equilibrium between Titanium Ions and Electrodeposition of Titanium in Molten Fluoride–Chloride Salt

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The Influence of Fluoride Anion on the Equilibrium between Titanium Ions and Electrodeposition of Titanium in Molten Fluoride–Chloride Salt

NaCl­KCl­TiClx was prepared via using titanium sponge to reduce titanium tetrachloride in a NaCl­KCl melt under a negative pressure at 1023K. The relationship between titanium valence states and [F]/[Ti] molar ratios was investigated with successive adding potassium fluoride in the pre-prepared NaCl­KCl­TiClx. It was found that the average valence of titanium ions tended to be stable around 3.0...

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ژورنال

عنوان ژورنال: MATERIALS TRANSACTIONS

سال: 2014

ISSN: 1345-9678,1347-5320

DOI: 10.2320/matertrans.m2014071